Perforate metal sheets



Aug. 21, 1962 D. B. PAU. 3,049,796

PERFORATE METAL SHEETS Filed July 2, 1957 2 Sheets-Sheet 1 IN1/EN DAVID B. PAL

his ATTORNEYS D. B. PALL PERFORATE METAL SHEETS 2 Sheets-Sheet 2 Aug. 21, 1962 Filed July l2, 1957 his BY 5MM/9h21 www ATTORNEYS.

3,049,796 PERFORATE METAL SHEETS David B. Pall, Roslyn Heights, N.Y., assigner, by mesne assignments, to Pall Corporation, a corporation of New York Filed .luly 12, 1957, Ser. N 671,586 14 Claims. (Cl. 29-1835) Present day problems of ltration, control of boundary layers in high velocity gas flow, de-icing airfoils, temperature control for normally severely heated parts and the like are being met increasingly -by the use of porous sintered metal particle layers, as described in U.S. Patent No. 2,554,343. In general, considerable difficulty has been encountered in providing such products to meet the critical factors of close control of uniformity in the number, size, and shape of the pores, and in tensile strength, ability to be worked as in machining and welding, and cost.

It has been suggested that perforate sheet materials having a myriad of uniformly and precisely dimensioned pores formed therein be employed. However, the preparation of these also has met with difficulties.

One method of preparing such material is to drill holes in a metallic sheet in the desired pattern. This is expensive, and quite difficult to do in thick sheet material when the pores are to be set on close centers.

Another method, which has been described in U.S. Patent No. 2,423,547 to Behlen, dated July 8, 1947, involves rolling a wire mesh screen to a fiat sheet. The use of a woven mesh screen is not practical in most instances because very ne laments are necessary for small pore openings to be provided, and such a screen material is therefore inherently fragile. Behlen worked out a method of utilizing the coarser wire screens, 100 mesh to the inch or less, Woven from a wire approximately 0.0045 inch in diameter, by rolling the screen to reduce the size of the holes. This material can be reduced to a pore diameter equivalent to that of a 180 or 200 mesh screen, but with fewer pores per square inch. The strength of the rolled mesh is no greater than that prior to rolling, hence lthe product is quite weak. Moreover, the Behlen method operates successfully only on very soft metals such as copper. If applied to stainless steel, the mesh is destroyed during rolling by the cutting laction of the wires on each other.

In accordance with the present invention, these difficulties are overcome by sintering the iilaments of the woven wire mesh screen to integrate them at some stage of the process. If the filaments are woven in a weave in which they are able to shift in their relative positions, or if the degree of rolling is such that the wires would tend to cut through each other, the filaments are integrated by sintering prior to deforming `as by rolling. If the filaments are woven in a weave in which they are stabilized against relative movement, the sinterng operation can be carried out after rolling, although, of course, there is no reason why the filaments cannot be sintered prior to rolling, if desired. This method makes it practical to prepare perforate metallic sheet products from screen materials formed of very ne wires, appreciably finer than is used in 100 mesh screen. In fact, screens of 450 mesh and smaller can be utilized in the process of the invention to provide perforate metallic sheet prod- 3,049,796 Patented Aug. 21, 1962 ucts having a relatively large number of pores in a uniform pattern and of a uniform porosity in a very thin sheet.

In certain cases the effect of the rolling operation can be imparted to the work by the application of pressure during sintering.

In accordance with the present invention, therefore, there are provided perforate metallic sheet products and methods of making the same wherein pores of uniform size and shape and in relatively large numbers relative to the total sheet areas are readily attainable at relatively low cost. Perforate products formed in Iaccordance with the present invention are also capable of production in a wide range of 'strengths and forms capable of passing extremely large volumes of uid. Moreover, if fines are entrained in the fluids the product is capable of stopping, without appreciable loss in capacity, relatively large quantities of all fines exceeding a predetermined size.

The pore diameter of the perforate metallic sheet products in accordance with the invention may range below 5 microns. The finest woven wire mesh screen that has been available has a pore opening of about 33 microns.

Thus, in accordance with the invention a perforate material having a pore opening less than ever before available in the finest woven wire mesh screen has been made possible. Depending upon the pore opening in the starting material, a Wide range of pore openings can be achieved, ranging from 5 to 45 microns in average diameter, utilizing to 450 mesh screen material.

To these ends, the present invention contemplates the use of metallic filaments interwoven in any weave style, with the relative positions of the filaments in the weave being initially stabilized either by characteristics of the weave itself or by integrating contacting surfaces of the interwoven filaments in a sintering operation. Once fixed in their relative positions or simultaneously with the sintering operation, the interwoven filaments are deformed by subjecting them to pressure normal to the plane of the product as by rolling, pressing, coining or the like, to establish numerous permanently attened coplanar surfaces on each face of the work and, at the same time, to enlarge the contiguous surface areas between the interwoven filaments. With the enlargement of the contiguous surface areas and the flattening of the faces, the size of the pores in the screen may be reduced by a controlled amount which usually bears a direct relationship to the overall diminution of thickness of the work as a result of the applied deforming pressure. The operation can be completed by further sintering, which may be under light pressure, to integrate the enlarged contiguous surface areas between the filaments, with the resulting product being a rigid metallic sheet having pores of precisely controlled size and shape.

Identical or non-identical sheets formed in generally the same manner can be brought together face to face and -fused together in yet another sintering operation, preferably under light pressure, to form a multiple layer sheet of still greater rigidity.

Pore openings of various configurations can be obtained, depending upon lthe type of weave of the starting materia-l. A square weave screen will give a straight through type of opening in which the pores run straight and roughly at right angles to the surfaces of the sheet. A Dutch weave, plain or twilled, will give an angled pore, in which the pore runs at an angle usually from 15 to 60 to the surfaces of the sheet.

Several products and methods in accordance with the present invention are described in detail below, having reference in one embodiment to the accompanying drawing in which:

FIGURE 1 is a plan view of a rigid perforate metallic sheet material;

FIGURE 2 is a View in transverse section taken on the line 2 2 of FIGURE l looking in the direction of the arrows;

FIGURE 3 is a plan view of a rigid perforate metallic sheet material;

FIGURE 4 is a view in transverse section taken on the line 4 4 of FIGURE 3 looking in the direction of the arrows;

FIGURE 5 is a view in transverse section taken on the line 5 5 of FIGURE 4; and

FIGURE 6 is a View in transverse section taken on the line 6 6 of FIGURE 4.

In general, the metallic filaments can be formed from any of a wide range of materials capable of being processed in the form of woven wire mesh, for example, stainless steel, such as type 304 or type 316 stainless steel, nickel and nickel alloys, such as Monel, N-l55 alloy and Hastelloy C, aluminum, silver and copper.

The Yusefulness of perforate sheet material for filtration canV be improved in certain situations in accordance with the present invention by incorporating permanent magnetic material in the sheet by utilizing filaments in the initial weaving operation formed of a material which can be magnetized to a high flux value. The finished perforate sheet product is then magnetized with alternate north and south poles on close centers, the pole direction 'being at right angles to the plane of the sheet. It has been found that a filter so formed removes extreme fines of magnetic material from fluid media passed therethrough. A second means for obtaining a magnetic filter is to use a woven wire cloth with a non-magnetic warp and a soft magnetic filling or weft. When the resulting sheet is placed in a magnetic field in a direction parallel to the warp, a north-south gap results between each neighboring pair of filling wires. Such a configuration is even more effective in removing fine magnetic particles than the one described above. It is, of course, equally possible to use a magnetic warp and non-magnetic filling.

With the initial weave stabilized, either by sintering or by the weave, the work can be subjected to deforming pressure of the order of 5000 to 200,000 lbs. per square inch, the pressure applied depending upon the ductility of the metal, normal to its surfaces as by rolling or coining, for example, to reduce yits thickness. In practice reductions in thickness from 5% to 85% of the initial thickness of the woven product have been carried out with beneficial results. The applied pressure results in a permanent deformation of the work by attening the undulations or nodes of the interwoven filaments in the two faces of the work, forcing attened material to encroach upon the holes in the mesh to decrease their size in precisely controlled amounts, and increasing the contiguous or contacting surfaces between the interwoven warp and weft filaments. The enlargement of these contiguous surfaces includes or encompasses the previously sintered contacting-surfaces at the points of crossover of the filaments. The work is then subjected to a sintering operation thereby to integrate or bond the enlarged contiguous surfaces between the interwoven filaments.

In the sintering operation the work is passed through a furnace in a non-oxidizing atmosphere such for example as a reducing atmosphere of hydrogen, carbon monoxide, or mixtures thereof, an inert atmosphere such as nitrogen, argon, helium, or combinations thereof, or a vacuum. A temperature at which the metal can be bonded to itself, near but less than the melting point of metal of which the filaments are formed, is used, a range from l000 F. to approximately 20 F. less than the melting point having been found useful for most purposes.

A perforate sheet material which has been so processed can, depending upon the degree of deformation, give a differing appearance in its tinal form. A square weave material compressed to a thickness of approximately 35% of the starting thickness for example has the general appearance of a sheet of solid metal through which rectangular holes have been machined.

In general, where metals are used which have very low yield strength after heating in the sintering temperature range, such for example as Monel, nickel and copper, it is advisable to accomplish only part of the compression in the first step, then after the last sintering operation to compress further, to the required pore size. In this way the final product can, by final work hardening, be made to have a high yield strength, still coupled with adequate ductility.

In one of its embodiments the invention contemplates the formation of a rigid perforate metallic sheet by preparing in a weaving operation, a plain or square weave mesh using metallic filaments. A plain Dutch weave can also be used. The wire mesh should be stabilized as to the relative positions of the metallic filaments. In the case of a simple square weave mesh in which both warp and weft filaments are equally spaced, the initial stabilization of the weave pattern can be effected by integrating the interwoven filaments at the crossover points by sintering.

Referring to FIGURE 1, there is shown a fragment 10 of a perforate sheet material formed in accordance with the process described above from a plain square weave wire mesh screen but deformed to decrease the thickness by less than 50%, thus retaining more of the identity of the original weave structure. The weave includes warp and weft filaments 11 and 12, respectively, which are deformed in the upper and lower surfaces 13 and 14, respectively. The deformed portions of the several filaments in each face of the sheet 10 are substantially coplanar, as best seen in FIGURE 2. Enlarged contiguous surfaces 15 appear between the interwoven and adjacent filaments 11 and 12 which have been joined by sintering to form the finished product. Defined by the interwoven deformed and sintered filaments are pores 16 of substantially uniform size throughout. The ports 16 are substantially rectangular in shape and pass straight through the sheet at right angles thereto.

Referring to FIGURE 3, there is shown a fragment 17 of a perforate sheet material formed in accordance with the process described above from a plain Dutch weave wire mesh screen but deformed to decrease the thickness lby considerably less than 50%, and less than the sheet material of FIGURES 1 and 2, thus retaining even more of the identity of the original weave structure. The weave includes weft and warp filaments 18 and 19, respectively, which are slightly deformed in the upper and lower surfaces 19a and 20, respectively. The deformed portions of the several filaments in each face sof the sheet 17 are substantially coplanar, as best seen in FIGURES 4 and 6. Slightly enlarged contiguous surfaces 21 appear between the interwoven and adjacent filaments 18 and 19 which have been joined by sintering either before, during or after deforming. Defined by the interwoven deformed and sintered filaments are pores 22 (FIGURE 4) of substantially uniform size throughout and at an angle to the plane ofthe sheet.

`In accordance with the present invention, two or more sheets of mesh treated in accordance with the process described above to form rigid perforate sheets can Ibe joined I together in face to face relation by a sin-tering operation to form a compound sheet. In order to avoid the appearance of undesirable interference patterns due to slight variations in the weave as between the two sheets and in order to keep permeability at a maximum, it is sometimes perferable 4to lay adjacent sheets of the perforate material so that the corresponding woven filaments in each lie at an angle to each other.

It is also possible to join by sintering operations, one, two or more rigid perforate sheets to a solid lor imperiorate backing sheet and if desired, the resulting product can be further deformed by the application of pressure normal to its surfaces as by coining or rolling operations to reduce further the overall thickness, the product then being resintered to integrate or join newly created c011- tiguous surfaces between the filaments. A porous sheet joined to a solid sheet backing can be used, among other uses, as a bearing.

It is possible, in accordance with the invention, to prepare rigid perforate sheets formed of metallic filaments using a complex weave. A twilled Dutch weave can be used in which each weft filament goes over and under a pair of warp filaments, the pairs alternating from one lweft filament to the next, or various special weaves such for example as a Ton-Cap weave in which the effective spaces between the filaments are relatively long and narrow. The various weaves described above can be relatively fixed or stabilized, if necessary, in a preliminary sintering operation to join contiguous surfaces between the interwoven filaments, subjected to deforming pressures normal to their surfaces, as by pressing, rolling or coining, to a thickness which `can in some instances be as small as one-third as the original starting thickness, and then resintering to join the enlarged contiguous surfaces.

lf desired, the tensile strength for such a material can be made higher in :one direction than it is in another, depending on the warp and weft count and filament diameters.

It should be understood that the complex weave products, suitably formed in accordance with the present invention into rigid perforate sheets, can be combined in multiple layers. By placing two layers of identically formed sheet materials in face to face relationship with the weave pattern at right angles, joining the two by sntering, deforming 'by the application of pressure normal to the surfaces, and joining again by resintering, a composite material of equal strength in all directions can be obtained. By placing two or more substantially identical sheets in face to face relationship with the weave pattern parallel, a product can be obtained having oriented strength. In this `connection it should be observed that unlike plain or square weave materials, products of excellent quality are obtained using complex weaves such for example as the Dutch weaves, when adjacent layers or sheets are mated with the weave patterns parallel.

In accordance with the invention, it is possible to prepare a stabilized weave pattern in which the initial sintering operation can be dispensed with. In a tightly woven Dutch weave, for example, in which the filaments are in lateral abuttinfr relationship so as to preclude relative movement during a rolling or coining operation, the work can be deformed, as by rolling or coining, without interp'osing a sintering ste In a relatively loosely woven square weave, it is believed that the considerable lateral spacing between adjacent filaments in both warp and weft affords an opportunity for lateral relative displacement which makes a preliminary sintering operation desirable.

In accordance with the invention it is possible to prepare a rigid perforate sheet which is extremely thin as well as fine in pore size. Beginning with a wire mesh of 325 count, sintered, deformed and sintered to achieve an average pore size of microns (from an original average pore size of 43 microns) a sheet of approximate` ly 0.001 inch thickness results. Similarly, a 200 x 1500 wire mesh using 00029/00013 inch diameter filaments and which has been rolled to an average pore size of 5 microns, has a thickness of appnoximately 0.003 inch. Such materials can be sintered if necessary to facing materials in order to provide the strength for mounting, to permit fabrication into tubes, welding or the like.

A representative process for making relatively fine and coarse materials, and for making a composite sheet in which the coarse material as a backing is sintered to the fine material as a facing, can be carried out as follows.

6 Example A A 325 x 325 square weave mesh using a 0.0014 inch diameter filament of type 304 or 316 stainless steel 1s sintered at 2350 F. and thereafter subjected to heavy deforming forces in a rolling mill. After rolling the Work is further deformed `by passing it through a pair of coming dies which coin a small area at a time, the work being moved slowly through the dies so that the whole area is uniformly reduced in thickness until the opening size has been reduced to an average of 2.0 microns, at which time the overall thickness will be about 0.0011 inch.

Example B A 60 x 60 square Weave mesh using a 0.011 inch filament of type 304 or 316 stainless steel is sintered at 2350" F. to fuse the filaments at their crossover points, and then deformed to reduce the thickness to 0.017 inch.

Example C The product of Example A having 20 micron holes is laid on a 60 x 60 mesh square weave made with .011 inch filaments and the two passed through a furnace `at 2350 F. in a sintering yoperation in order to join them together.

`In order to further improve the union, the work on issuing from the furnace may be passed through ra deforming operation in la rolling mill to reduce the thickness by 0.001 to 0.002 inch and then resintered `at 2350 F. The final product has `been found to have a flow capacity which is reduced by less than 10% from that of the coined 325 mesh sheet, taken alone, has an overall thickness of approximately .027 inch, and has excellent strength and rigidity while retaining enough formability such that i-t can be readily formed into tubes and welded, for example.

Example D `In Ianother example of a composite material, two layers of 12 x 64 plain Dutch weave mesh using 0.023/ 0.0165 inch filaments of type 316 stainless steel `are placed together, and sintered at 2350 F. Upon issuing from the sintering furnace, the work is passed through a rolling mill in order to reduce the overall thickness to 0.050 inch. A 50 x 300 twilled Dutch weave using 0.049/ 0.0036 inch filaments of type 316 stainless steel is sintered at 2350 F. and thereafter passed through a rolling mill in order to reduce the pore size to a value such that the maximum glass bead which will pass through it in water suspension is 25 microns. The Ideformed work is then placed on top of the 0.050 inch thick sintered Iassembly and the two passed through ya sintering furnace at 2350 F. Upon issuing, the resultant composite is reduced in thickness by 0.001 to 0.002 inch by rolling and then resintered. The resultant composite material can readily be rolled, deformed, welded, or the like, and simple discs of this material can be pressed, land fitted into cavities, where they will withstand high differential iiuid pressures thereacross.

Example E A fine 60 x 60 square weave using a 0.011 inch diameter filament of Monel is sintered at 2050 F. and deformed under pressure. A coarse 8 x 8 square weave using a 0.050 inch :filament of Monel is sintered at 2050u F. and deformed under pressure. Ihe two are integrated or joined together in face to face relationship -by sintering with corresponding filaments Iat an angle to each other.

Example F at 235 0 F. The resultingcomposite sheet, -due to i-ts complex mternal structure, has higher filtering capacity than the Dutch twilled Weave by itself.

'In the sintering together of two layers of wire mesh .material in the practice of the present invention and 1n the initial sintering of the weave patterns o-f each, it

has been found that the application of a slight pressure can be used to effect deformation and to improve the integration. Pressures of approximately lbs. per square foot 'and more upon the work being sintered, las by imposing metal weights thereon, have been found to afford excellent results. in order to avoid adherence of the objects Ibeing sintered to the neighboring layers of material, they are separated by layers of suitable inorganic material, which may be metal oxides or `silicates or combinations thereof which are not chemically Iaffected by the sintering atmosphere.

The sintered, rolled, and woven wire of this invention may also lbe combined by sintering together with other porous media such as the porous stainless steel disclosed in US. Patent No. 2,554,343, 'or perforate media such las sheet material containing holes mechanically or chemically (etching) formed. They can also be combined with electroformed nickel or nickel-copper or `copper screens.

When a stainless steel rolled and sintered sheet .material is combined with electroformed nickel, due to interdilfusion which occurs at high temperature, the nickel is converted to a chromium iron alloy, the composition of which can be brought very close to that of .the stainless steel if the time at temperature is suciently prolonged, and if the mass of stainless steel greatly exceeds that of the nickel. Such nickel screens can be formed with as many as 1,000,000 .to 4,000,000 holes per square inch but they are in themselves very thin, foil-like materials of no practical application in filtration. `Co-sintering which bonds these to a strong rigid sintered and rolled woven stainless material represents, therefore, a very useful technique.

`In another variation of this technique, the electroformed nickel is plated with 5 to 25% by Weight of chromium prior lto sintering. In this way, fa high chromium content alloy, very resistant to attack by a variety of chemical reagents, and to atmospheric corrosion, is obtained with a shorter sintering cycle.

The perforate metallic sheet materials in accordance with the invention which can be made with pores having axes normal to the plane of the sheet and smaller than a 33 microns square, have a higher flow capaci-ty for -an -avenage pore opening diameter per square inch than a porous material made from a sintered metal powder. It is thought that this is due to the greater uniformity of hole size of material of the invention. The simple iiow path through the perforated metallic sheet material also contributes to high flow, compared with the tortuous path through a sintered powder porous metal. When properly selected wire combinations are used, the perforated metallic lsheet material can have ftwo or more times as many effective holes per unit area, compared with materials made from powder, contributing to higher flow nate for equal -pore size. The perforate metallic sheets can also be made 4by the present invention to `contain more than 225,000 pores per square inch, each pore consisting of a direct opening through the sheet material at an angle 4between l5" and 90 tothe plane thereof, each pore being suliiciently small t-o hold back spherical particles of 5-10 microns. Such sheets also have substantially higher flow capacity for equal maximum -pore size, compared with filter media made from powder.

Utilization of the various woven structures according to the invention results in a highly uniform pore structure and enables more consistent structures to be obtained than in other methods of fabrication. Further, it permits a single-layer structure to be produced having pores at an angle to the layer, or perpendicular' thereto, as desired. ln addition, a single layer of fine porous structure may be bonded to another layer of coarser mesh. as described above.

The perforate metallic sheets of the invention are particularly useful in tangential flow filtration wherein the stream of liquid to be filtered is fiowed across the surface of the filter and a portion passes through the filter while another portion flows past the filter and thus bypasses it. This type of filter is used in airplane engine carburetors.

The perforate metallic sheet materials of the invention are also characterized by an exceedingly high tensile strength compared to porous structures formed of sintered metal particles. The tensile strength of a porous metal filter 1/16 inch thick having a flow capacity of l0 feet per second at 2 psi. is of the order of 6000 to 8000 p.s.i. In contrast, the perforate materials of the invention of the same iow capacity can be made with tensile strength of 25,000 p.s.i. or more.

While representative embodiments ofthe invention have been described above, it will be apparent to those skilled in the art that various combinations of weave patterns, and combinations of processing steps can be carried out within the scope of the present invention, which should not, therefore, be regarded as limited except as defined by the following claims.

l claim:

l. Fluid-permeable metallic sheet material comprising a continuous homogeneous integral network having a pore system substantially corresponding to a wire mesh fabric, comprising interwoven metallic warp and weft filaments in contact with each other Warp to weft and weft to weft and defining `therebetween a regular system of pore openings of substantially uniform diameter of less than about 0.075 inch, the filaments being deformed at their points of contact so as to have a lesser height and a greater width at those points to form enlarged portions extending laterally in the plane of the sheet, and being homogeneously and uniformly united by inter-diffusion of solid metal from adjacent filaments at said points and enlarged portions throughout .the network to form a continuous homogeneous integral piece of metal.

2. Fluid-permeable metallic sheet material in accordance with claim l in which at least a portion of said metallic filaments are of magnetic material.

3. Fluid-permeable metallic sheet material in accordance with claim 2 including filaments of nonmagnetic material, the magnetic filaments running in one direction only.

4. Fluid-permeable metallic sheet material in accordance with claim l including an imperforate metal sheet uniformly united to said sheet material by interdiffusion of metal therebetween.

5. Fluid-permeable metallic sheet material in accordance with claim l including a perforate metal sheet uniformly united to said sheet material by inter-diffusion of metal therebetween.

6. Fluid-permeable metallic sheet material in accordance with claim l including a layer of metallic powder uniformly united thereto by interdiffusion of metal.

7. Fluichpermeable metallic sheet material in accordance with claim l comprising a plurality of such sheet materials uniformly united together, one of said sheets having relatively coarse pore openings and filaments uniformly united in pore-connecting juxtaposition by interdiffusion of metal with filaments of a sheet having smaller pore openings.

8. Fluid-permeable metallic sheet material in accordance with claim 7, the two sheet materials having the same weave structure and disposed with the weave patterns at an angle to each other.

9. Fluid-permeable metallic sheet material in accordance with claim 7, the two sheet materials having a different weave structure.

l0. Fluid-permeable metallic sheet material in accordance with claim l in which the filaments in at least one of the faces of the material are sufiiciently fiattened to establish tight lateral abutment of such filaments about each of the pores, forming a substantially fiat continuous metallic surface on that face, the surface being pierced by the pores.

11. Fluid-permeable metallic sheet material in accordance with claim l0, the laterally abutting flattened por- 9 tions of such surface being uniformly united by interdiffusion of metal from adjacent filaments.

12. Fluid-permeable metallic sheet material in accordance with claim 1, in which the laments are interwoven in a square weave.

13. Fluid-permeable metallic sheet material iu accordance with claim 1, in which the laments are interwoven in a Dutch weave,

14. Fluid-permeable metallic sheet material in accordance with claim 1, in which the pore openings are less than about 0.02 inch and the laments less than about 0.011 inch in diameter.

References Cited in the file of this patent 10 2,271,829 Powers Feb. 3, 1942 2,327,184 Goodlow Aug. 17, 1943 2,374,756 Kisch May 1, 1945 2,423,547 Behlen July 8, 1947 2,661,029 Walsh Dec. 1, 1953 2,694,852 Rogers Nov. 23, 1954 2,711,828 Webb June 28, 1955 2,781,097 Nold Feb. 12, 1957 2,820,985 Cresswell Jan. 28, 1958 FOREIGN PATENTS 324,924 Great Britain Feb. 3, 1930 OTHER REFERENCES NACA Research Memorandum (NACA RM. E51- H23), published November 13, 1951, by E. R. G. Eckler, Martin R. Kinsler, pages 1-b, 11-14 and 18-22.

The Guilds EngineerFourth Issue-1953-The City & Guilds College- University of London.

Proceedings of the IInstitution of Mechanical Engineers 20 (1954) Volume 16s Number 34, pages s37-846- Iron & Steel Symposium Special Report-Number 43, July 1952, page 351. 

